Carborane相关论文
IN-PP86:Reaction of a 16-electron CpCo Half-sandwich Complex Containing a Chelating1,2-Dicarba-closo
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IN-PP70:Reactions of a 16-electron Half-sandwich Ruthenium Complex Containing a Chelating 1,2-Dicarb
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The most widely studiedof imidazoliumcyclophanebecause of the positive charge on the imidazolium,which makes the C-H act......
邻-碳硼烷的选择性官能团化是碳硼烷化学中的一个热点.由于邻-碳硼烷特殊的三维芳香性,其在聚集诱导发光材料、非线性发光材料以及......
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Carboranes are a class of polyhedral boron hydride clusters in which one or more of the BH vertices are replaced by ......
Transmetalation of carborane-fused zirconacycles to Cu(Ⅱ) induces the C-C coupling reaction to form four-membered rings......
Reaction of [η5:σ-Me2C(C5H4)(C2B10H10)]Ru(NCCH3)2 (1) with R1C≡CR1(R1 = Et, Ph) in toluene at 80 °C yielded orga......
The metal-carbon bonds in metal-carboranyl and metal-carboryne complexes behave very differently from those in classical......
Geometrical optimization and theoretical calculation of the vibrational frequencies have been performed for C2B10H12, NB......
Regioselective B-H/C-H Bond Activation at Azo-Substituted Carboranes Induced by Half-Sandwich Iridiu
We report herein a practical approach for regio-selective B-H/C-H bond activation at azo-substituted carboranes.The reac......
利用非等温DSC对o-碳硼烷双酚环氧树脂/4,4′-二苯砜二胺(DDS)以及m-碳硼烷双酚环氧树脂/DDS体系的固化反应过程进行了研究,并根据......
Synthesis and Crystal Structure of a B-H Activated Compound Containing a Furan Ring and an ortho-Car
本文通过对荣华二采区10...
Synthesis, Structure and Characterization of a Novel Asymmetrical Half-sandwich Binuclear Iron Carbo
本文通过对荣华二采区10...
Broad Scope Extra-Annular [4 + 2] Cycloaddition of o-Carboryne with Styrenes: Efficient Route to Car
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
Reaction of o-Carboryne with Furans: Facile Synthesis of Carborane-Fused Oxanorbornenes and Their De
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
Synthesis and reaction of 16-electron CptRh halfsandwich complexes containing 1,2-dichalcogenolate c
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
Synthesis and Characterization of Carborane-containing Poly(hydroxy ethers) with Excellent Thermal S
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
Synthesis and Characterization of Fluorinated Polyurethane Containing Carborane in the Main Chain: T
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
16e半夹芯化合物CpCo(S2C2B10H10)(Cp:cyclopentadienyl) (1)与炔烃HC≡ CC(O)Fc(Fc:ferrocenyl)在物质的量之比为1:1时反应生成化......
Synthesis and reaction of 16-electron CptRh halfsandwich complexes containing 1,2-dichalcogenolate c
The reactions of [CptRhCl((-Cl)]2 (1) (Cpt = tBu2C5H3) with Li2E2C2B10H10 (E = S, Se) lead to the green 16-electron dich......
Synthesis, Structure and Characterization of a Novel Asymmetrical Half-sandwich Binuclear Iron Carbo
Halfsandwich iron dicarbonyl complex [η5-C5H3(t-Bu)2]Fe(CO)2Cl(1) reacts with 1, 2-dilithium diseleno carborane Li2Se2C......
碳硼烷改性有机硅树脂是一种耐热性能优异的高分子材料,具有广阔的应用前景。然而由于聚合单体碳硼烷改性硅氧烷的合成条件苛刻,严......
有机金属含硫族化学是现代无机化学和配位化学研究中的重要研究领域之一,它充分展示了硫族元素和金属中心配位的多样性.综述了各类......
根据基本定义和专门的命名规则，建议统-carborane的中文定名为“碳硼烷”，C2B10H12和C2B5H7分别命名为“二碳代-闭式-十二硼烷”（其异......
半夹芯16e化合物CpCoS2C2810H10（1）与FeC（O）C≡CH反应得到两个不合钴的产物2-3。2-3含有一个与硫原子相连的VeC（O）-CH=CH单元和一个与碳......
以甲基丙烯酸（碳硼烷甲氧乙基）酯为接枝单体，通过自由基乳液接枝处理真丝，在真丝丝素大分子上引入聚甲基丙烯酸（碳硼烷甲氧乙基）酯接枝链......
Synthesis, Structure and Characterization of a Novel Asymmetrical Half-sandwich Binuclear Iron Carbo
Halfsandwich iron dicarbonyl complex [η5-C5H3(t-Bu)2]Fe(CO)2Cl(1) reacts with 1, 2-dilithium diseleno carborane Li2Se2C......
利用Ｇａｕｓｓｉａｎ９４从头计算程序在６－３１Ｇ基组下对二十面体碳硼烷Ｃ２Ｂ１０Ｈ１２、ＣＢ１１Ｈ１２＾－及其衍生物ＣＢ１１Ｈ１１Ｂｒ＾－进行了从头计算，结果表明，在亲电取代反应中，杂原子Ｃ具有对、空间定位效应，取代......
利用密度泛函方法在B3LYW6—31G（d）水平上对1，2-C2B10H12的两种异腈类衍生物的结构特性进行了研究．结果表明，1，2-C2B10H11NC的活性较强；1，2......
八羰基二钴Co2(CO)8与叔丁基取代的环戊二烯反应,可以得到半夹心结构的羰基钴化合物CptCo(CO)2(2)(Cpt=η5-tBuC5H4),化合物(2)与......
16e半夹芯化合物CpCo（S2C2B10H10）（Cp：cyclopentadienyl）（1）与炔烃HC≡CC（O）Fc（Fc：ferrocenyl）在物质的量之比为1∶1时反应生成化合物CpCo（S2C2B......
碳硼烷双膦配体L1分别与三苯基膦氯化镍（NiCl：（PPh3）2）和1，5．环辛二烯氯化铱（IrCl（COD））在空气中反应生成含巢式碳硼烷膦氧配体的镍、铱化合物......
半夹芯16e化合物CpCoS2C2B10H10（Cp：cyclopentadienyl）（1）与2-呋喃炔酮在物质的量比为1：1.5时反应分离得到1个顺磁性化合物CpCoS2C2B10H9......
在路易斯酸催化下,碳硼烷分别与对氰基溴化苄、三苯基膦在甲苯溶液里回流,前者反应中,制备得碳硼烷的硼端与对氰基苄基中的亚甲基......
邻位碳硼烷分别与正丁基锂、硫粉和Me4Cp Co（CO）I2反应合成得到半夹芯16电子碳硼烷化合物Me4Cp Co S2C2B10H10（1）。1与二茂铁炔酮在二......
以甲基丙烯酸羟乙酯、溴丙炔和癸硼烷等为原料制得1-甲基丙烯酰氧乙氧甲基碳硼烷（PMAC）,再依次与二甲基氯硅烷、氢氧化钠与磷酸二氢......
碳硼烷是一类优异的耐高温原料,POSS是一类性能优异的耐原子氧化合物。本文利用硅氢加成的方法,将两者有机结合,合成了体型交联型......
以m-碳硼烷为原料,通过Ullmann反应和脱甲基反应获得1,7-二(4-羟基苯基)-m-碳硼烷(1),进一步得到热固性的碳硼烷酚醛树脂(preP1),......
碳硼烷因其独特的性质及其在应用方面的广阔前景,受到化学家们的广泛关注.本文对金属碳硼烷、碳硼烷金属配合物抗肿瘤活性的研究进......
A new compound[CpCo(Se_2C_2B_(10)H_9)CH_2C(O)C_4H_3O]has been synthesized and characterized by elemental analysis,IR spe......
