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Li/SOCl_2电池体系具有比能量高、放电平稳、贮存寿命长和工作温度范围宽等优点,在航空、军工等领域有广阔的应用前景。国内外对该体系的电化学性质和工艺技术做过大量研究,但对其反应机理尚不清楚,对电池反应式也缺乏一致的观点。采用常规的电化学方法很难确切判断反应复杂的中间产物及其性质。各种波谱学方法虽曾被用于研究Li/SOCl_2体系
Li / SOCl_2 battery system has the advantages of high specific energy, stable discharge, long storage life and wide operating temperature range. It has broad application prospects in aviation, military and other fields. At home and abroad, a great deal of studies have been done on the electrochemical properties and process technology of the system. However, the reaction mechanism is not clear yet and there is a lack of consistent view on the battery reaction. It is difficult to determine accurately the complex intermediates and their properties by conventional electrochemical methods. Various spectroscopic methods have been used to study Li / SOCl_2 system