Dinuclear相关论文
The very recently developed homometallic lanthanide-based single-molecule magnets(SMMs)or single-ion magnets(SIMs)have r......
2,6-Dimethoxyphenol-Bridged Dinuclear Dy2 Single-Molecule Magnets:Synthesis,Structure,and Magnetic S
The very recently developed homometallic DyⅢ-based single-molecule magnets(SMM)or single-ion magnets(SIM)have received ......
Slow Magnetic Relaxation Behaviors within twoDy2Single-MoleculeMagnetswith Single-crystal to Single-
A dinucleardysprosium complex [Dy2(DMOMP)2(DBM)4]2·CHCl3(1)(DMOMP = 1-methyl-3,5-dimethoxy-4-hydroxybenzene)bridged by ......
Homoleptic mononuclear and binuclear ruthenium carbonyls Ru(CO)n(n=3―5) and Ru2(CO)n(n=8,9) have been investigated usin......
Di-and tetranuclear heterometallic Cu~Ⅱ -Ln~Ⅲ complexes (Ln=Gd and Dy): Synthesis, structure and mag
Four 3d-4f heterometallic complexes, [CuⅡ LnⅢ (bpt) 2 (NO 3 ) 3 (MeOH)] (Ln = Gd, 1; Dy, 2; bptH = 3,5-bis(pyrid-2-yl)......
In the title coordination compound,[Cu(HDPPZC)(SO4)(H2O)]2 (1,HDPPZC=dipyrido[3,2-a:2,3-c]-phenazine-2-carboxylic acid),......
Cyanide-bridged complexes based on dinuclear Cu(Ⅱ)-M(Ⅱ) [M=Pb and Cu] building blocks: Synthesis, cr
Four cyanide-bridged heterometallic complexes {[CuPb(L 1 )][Fe III (bpb)(CN) 2 ]} 2 ·(ClO 4 ) 2 ·2H 2 O·2CH 3 CN (1),......
Synthesis,Crystal Structure and Electrochemical Property of a Dinuclear Manganese(Ⅱ) Complex [Mn_2(C
One dinuclear manganese(II)complex [Mn2(C12H8N2)4(C8H5O4)2](C8H4O4)·H2O has been synthesized with o-phthalic acid and 1......
The synthesis and molecular structure of a new dinuclear copper(Ⅰ) complex [Cu(dppb)(NO 3)] 2 are reported.The compound......
A Cu(II) complex of tetra(3,5-diphenyl pyrazole) [Cu(C15H12N2)2Cl2]2 (1) was synthesized, and its structure was determin......
The two three-dimensional oxo-bridged lanthanides , with Ln=Ho3+ (1); Gd3+ (2), are isomorphous. They have layer-type st......
Five lanthanide complexes of Ln2(dpdc)2(tpy)2(NO3)2(H2O)2 [Ln=La(1),Ce(2),Pr(3),Sm(4),Gd(5),H2dpdc=2,2’-biphenyldicarbo......
Combination of Lindqvist-type Tungstovanadates and Transition Metal Clusters under Hydrothermal Cond
Two novel organic-inorganic heteropolyoxometalate compounds [{Cu(1,10- phen)OH}_2]_2[V_2W_4O_19]·6H_2O (1) and [Co(1,10......
ADSORPTION OF TiCl_4 AND ELECTRON DONOR ON DEFECTIVE MgCl_2 SURFACES AND PROPYLENE POLYMERIZATION OV
The formations of defective MgCl2 surfaces, and subsequent adsorption of Ti species and electron donor, as well as propy......
Hydrothermal syntheses and characterization of three lanthanide coordination complexes constructed b
Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2’-biphenyldicarboxylic acid and tpy= 2,......
Static field induced magnetic relaxations in dinuclear lanthanide compounds of [phen_2Ln_2(HCOO)_4(H
Two dinuclear lanthanide (Ln) complexes, formulated as [phen2Ln2(HCOO)4(HCOO)2-2x(NO3)2x](1, Ln=Gd and x=0.52; 2, Ln = E......
A novel 1,2,3-triazolyl-containing ligand(H2L) with long donor arms extending from the central pyridyl linker was synthe......
Synthesis, Crystal Structure, DNA Binding and Catalytic Activities of a New Unsymmetrical Macrocycli
An unsymmetrical macrocyclic dinuclear Zn(II) complex, [Zn2(H0.5L)(OAc)](ClO4)1.5(1, H2 L is the condensation product be......
Syntheses, Structures and Fluorescent Property of Two Cd(Ⅱ) 3D Coordination Polymers with Mixed Liga
Two new coordination polymers, [Cd(N3)2(Baep)1/2]n(1) and [Cd2(N3)4(CH3OH)(Bapp)1/2]n(2) (Baep=1,4-bis(2-aminoethyl)pipe......
A dinuclear copper complex [Cu2LCl2](ClO4)2(L = 2,2’-(piperazine-1,4-diyl)bis-(N,N-bis(pyridine-2-ylmethyl)ethan-1-amin......
Construction and Photoluminescence Properties of Zn(Ⅱ)/Cd(Ⅱ) Complexes with 4-Amino-3,5-propyl-1,2,4
Reaction of ZnCl2 and 4-amino-3,5-propyl-1,2,4-triazole(dpatrz) or CdCl2, NaN3 and dpatrz, in aqueous solution at room t......
Synthesis, Crystal Structure and Properties of a Dinuclear Cobalt(Ⅱ) Complex [Co_2(α-furacrylato)_4(
A dinuclear cobalt(Ⅱ) complex [Co2(α-furacrylato)4(Phen)2(H2O)]·C2H5OH has been synthesized with α-furacrylic acid a......
Herein reported is an example of one-dimensional coordination polymer [CoII(3,5-DBsq)2(dpg)]·(3,5-H2DBcat)2 (1) (3,5-DB......
One novel 3D 3d-4f coordination polymer, [LaZn(glc)(ox)2(H2O)2]n (1, glc = glycinate, ox = oxalate), was obtained by the......
The reaction of bis(1,2,4-triazolyl-4-yl) (btr) and MnClO4·6H2O gave rise to a Mn(Ⅱ) complex comprised of unprecedente......
Synthesis and Crystal Structure of a Cu(Ⅱ) Complex with Reduced Schiff-base N-(2-Hydroxybenzyl)-D,L-
A new complex [Cu2(sala)2(H2O)2(4,4’-bipy)]·H2O (sala = N-(2-hydroxybenzyl)- D,L-alaninate, 4,4’-bipy = 4,4’-bipyrid......
A New Dinuclear Gadolinium Complex Constructed from p-Phenylenediamine-N,N,N′,N′-tetraacetic Acid an
Routine solution reaction of Gd3+ and p-phenylenediamine-N,N,N′,N′-tetraacetic acid (p-PhDTA) yields a dinuclear compl......
Syntheses and Crystal Structures of Copper(Ⅱ) and Nickel Complexes with 1,2,3-Triazole-carboxylic Ac
Three novel complexes [Cu(L1)2(H2O)2] (1), [Ni(L1)2(H2O)2]·(H2O)4(2,HL1=5-methyl-1-(4-methylphenyl)-1,2,3-triazole-4-ca......
Synthesis, Crystal Structures and Catalysis of Dinuclear Cd(Ⅱ) Complexes Bridged by Unusual (N,O,O′)
Four dinuclear amino acid cadmium(II) complexes [Cd2(tren)2(dl-alaninato)](ClO4)3·H2O(I), [Cd2(tren)2· (l-alaninato)](......
Di-and tetranuclear heterometallic Cu~Ⅱ-Ln~Ⅲ complexes (Ln=Gd and Dy): Synthesis, structure and magn
Four 3d-4f heterometallic complexes, [Cu~ⅡLn~Ⅲ(bpt)2(NO3)3(MeOH)] (Ln = Gd, 1; Dy, 2; bptH = 3,5- bis(pyrid-2-yl)-1,2,......
Syntheses of bimetallic lanthanide bis(amido) complexes stabilized by bridged bis(guanidinate) ligan
A series of bimetallic lanthanide bis(amido) complexes stabilized by bridged bis(guanidinate) ligands {[(Me3Si)2N]2Ln[(R......
A new dinuclear copper(Ⅱ) complex [Cu(CH3COO)(C7H5N4)(H2O)]2·3.5H2 O has been hydrothermally synthesized with copper a......
Synthesis,Crystal Structure,Spectroscopic Characterization,Thermal Stability and Magnetic Properties
A new copper(Ⅱ) complex [Cu2(MNA)2(2,2‘-bipy)2]·2.5H2 O with methy-5-norbornene-2,3-dicarboxylic acid(MNA) and 2,2’-......
Synthesis, Crystal Structure, and Magnetic Properties of a New Dinuclear Iron Complex with Schiff Ba
A new dinuclear iron(Ⅲ) complex has been synthesized and structurally characterized by X-ray crystallography: [FeⅢ2(L)......
A new Eu(III) complex from 2,2’-bipyridine(2,2’-bipy) and 1,3,5-triazine-2-4,6-tri(L-alanine)(H3L), {[Eu(L)(2,2’-bipy......
A new zinc(Ⅱ) compound, [Zn(BTA)(UCA)]n(1, HBTA = 1,2,3-benzotriazole, HUCA = 4-imidazoleacrylic acid), has been synthe......
The tridentate ligand DPA-Me(2) was readily prepared from DPA(DPA = 2,2-dipicolylamine) in high yield. The mixture of 2 ......
Syntheses and Crystal Structures of Cd(Ⅱ) and Ni(Ⅱ) Complexes Containing Flexible Sulfide and Nitrog
Two new coordination polymers [Cd(EBLA)(ip)(H2O)](1) and [Ni(EBSA)(im)2(H2O)]n(2) were synthesized by hydrothermal and s......
Synthesis, Crystal Structure and Luminescent Property of a Dinuclear Cadmium Complex Based on 1,2,3,
A complex [Cd2(tbb)Cl4]·4DMF·3H2O, where tbb is 1,2,3,4-tetra(1H-benzo[d]imidazol-2-yl)butane, was synthesized and cha......
Cyanide-bridged single molecule magnet based on a manganese(Ⅲ) complex with TTF-fused Schiff base li
Reaction of [Mn(TTF-salphen)][OAc](TTF-salphen2-=2,2’-((2-(4,5-bis(methylthio)-1,3-dithiol-2-ylidene)-1,3-benzodithiole......
Efficient photocatalytic properties of a dinuclear iron complex with bis[2-hydroxybenzaldehyde]hydra
A novel photooxidative system for degrading toxic organic pollutants is reported.A new complex of Fe_2L_3(L = bis[2-hydr......
Synthesis and Crystal Structure of a Two-dimensional Cadmium Complex Based on Terephthalate and 1-Me
The title complex, Cd(MeHbibzim)(1,4-bdc)n (1, MeHbibzim = 1-methyl-2,2’- bibenzimidazole, 1,4-bdc = terephthalate), wa......
Synthesis and cytotoxicity of dinuclear platinum(Ⅱ) complexes of(1S,3S)-1,2,3,4-tetrahydroisoquinoli
A series of novel dinuclear platinum(Ⅱ) complexes with(1S.3S)-1,2,3,4-tetrahydroisoquinolines as the ligands were synth......
Syntheses, Crystal Structures and Properties of Two Cd(Ⅱ) Coordination Polymers with Mixed Ligands o
A new ligand 2,5-di(pyridin-4-yl)benzaldehyde (L) was synthesized by the reaction of pyridin-4-yl-boronic acid with 2,5-......
A series of 3D lanthanide complexes based on H bond and halogen-halogen interactions:Synthesis, stru
Four lanthanide coordination complexes, namely, [Ln(2,3-DClBA)_3(5,5’-dmebipy)(H_2O)]_2(Ln=Sm(1), Eu(2), Dy(3), Ho(4));......
Syntheses,Crystal Structures and Magnetic Studies of Heterobimetallates Based on Paramagnetic Ruthen
The syntheses, crystal structures and magnetic properties of two cyano-bridged heterobimetallic compounds prepared from ......
Mononuclear and Dinuclear Yttrium Complexes Supported by Pyrrolide Ligands: Syntheses, Structures an
The syntheses, structures and catalytic activities of two yttrium complexes supported by pyrrolide ligands are reported.......
Two Novel Complexes Based on N-N Bridged Ligand:Syntheses,Crystal Structures,Fluorescence and Magnet
Two novel coordination compounds,1[Zn_4(L_1)_4(NO_3)_2(H_2O)_2](NO_3)_2·2H_2O and 2[Mn_2(L_2)_2(DMF)(H_2O)_3](ClO_4)_2......
