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A novel complex ZnTPPL1·3DMF 1(TPP = tetraphenylporphyrin,L1 = N-(4-(9-carbazolyl) phenyl)-N,N-di(4-pyridyl)amine) was prepared by a hydrothermal method and characterized by elemental analysis,IR,and single-crystal X-ray diffraction analysis.Compound 1 crystallizes in triclinic,space group P1 with a = 13.3082(2),b = 14.3276(2),c = 18.6120(3) ,α = 109.853(1),β = 95.054(1),γ = 98.832(1)°,V = 3260.57(9) 3,Z = 2,Dc = 1.334 g/cm3,C81H69N11O3Zn,Mr = 1309.84,μ(MoKα) = 0.438 mm-1,F(000) = 1372,GOF = 1.159,the final R = 0.0482 and wR = 0.1479 for 12091 observed reflections(Ⅰ > 2σ(Ⅰ)).Crystal structure analyses revealed that L1 utilizes one pyridyl N atom to bind Zn via axial coordination,affording a 1:1 complex.The binding constant was estimated to be 1.74(7) × 104 M-1 from electronic spectra measurements.
A novel complex ZnTPPL1 · 3DMF 1 was prepared by a hydrothermal method and characterized by elemental analysis (TPP = tetraphenylporphyrin, L1 = N- (4- (9- carbazolyl) phenyl) -N, , IR and single-crystal X-ray diffraction analysis. Compound 1 crystallizes in triclinic space group P1 with a = 13.3082 (2), b = 14.3276 (2), c = 18.6120 ), β = 95.054 (1), γ = 98.832 (1) °, V = 3260.57 (9) 3, Z = 2, Dc = 1.334 g / cm3, C81H69N11O3Zn, Mr = 1309.84, μ (MoKα) = 0.438 mm -1, F (000) = 1372, GOF = 1.159, the final R = 0.0482 and wR = 0.1479 for 12091 observed reflections (I> 2σ (I)). Crystal structure analyzes revealed that L1 conversion one pyridyl N atom to bind Zn via axial coordination, affording a 1: 1 complex. The binding constant was estimated to be 1.74 (7) × 104 M-1 from electronic spectra measurements.