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应用差示分光光度法研究了牛红细胞Cu2Zn2SOD的紫外光谱,归属和讨论了酶活性中心金属离子与配体间全部电荷转移谱带,给出了相应的配体轨道光学电负性,特别研究了涉及Zn2+的电荷转移谱带.
The UV spectra of Cu2Zn2SOD in bovine erythrocytes were studied by differential spectrophotometry. All the charge-transfer bands between the metal ions and ligands in the active center of the enzyme were assigned and discussed. The corresponding optical orbital optical properties of the ligands were given. In particular, Charge transfer bands involving Zn2 +.