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介绍了国家杰出青年科学基金项目“含金属团簇基元超分子聚合物的设计合成及其光电性能研究”的背景。国内外现状、发展趋势、拟开展的研究工作和预期的目标。主要研究内容包括:将金属原子以三角形(M_3)、四边形(M_4)、六边形(M_6)、八面体(M_6)、立方体(M_8)或二十面体(M_(13))形成的团簇活化后构成基本活性单元,设计合成含金属团簇基元的具有光电性能的一维、二维或三维超分子聚合物。应用结构化学研究手段,研究它们的组装规律、空间结构、电子结构及其与物理化学性能的关系,研究电子在金属链或网间传递的过程及其金属相互作用的方式与固体材料性能的关系,寻找这些化合物在光电等材料领域中的可能应用。
This paper introduces the background of the project “Design, Synthesis and Optical and Electrical Properties of Supramolecular Polymers Containing Metal Clusters” funded by National Outstanding Youth Science Foundation. The status quo at home and abroad, the development trend, the research work to be carried out and the expected goal. The main research contents include: clusters of metal atoms formed by triangular (M_3), quadrilateral (M_4), hexagonal (M_6), octahedral (M_6), cubic (M_8) or icosahedron (M_ (13) Activated to form the basic unit of activity, the design and synthesis of metal cluster-containing elements have the photoelectric properties of one-dimensional, two-dimensional or three-dimensional supramolecular polymer. The application of structural chemistry research methods to study their assembly rules, spatial structure, electronic structure and its relationship with the physical and chemical properties of the electron in the metal chain or network transfer process and the interaction between the metal and the relationship between the properties of solid materials , Looking for these compounds in the field of optoelectronics and other possible applications.