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在水溶剂中,采用水热法合成了单核含氮配体镍配合物[Ni(phen)(SO_4)(H_2O)3]·H_2O(phen=1,10-邻菲罗啉)。采用X射线单晶衍射和元素分析等方法对配合物进行了表征。X射线单晶衍射表征结果表明,该配合物晶体属于三斜晶系,空间群为P1。晶体学参数:a=7.9829(6),b=8.5402(7),c=11.5164(9),α=91.636(2),β=91.837(2)°和γ=104.670(2)°,V=758.61(10)~3,Z=2。
In water solvent, the mononuclear nitrogen-containing ligand nickel complex [Ni (phen) (SO 4) (H 2 O) 3] · H 2 O (phen = 1,10-phenanthroline) was synthesized by hydrothermal method. The complex was characterized by X-ray single crystal diffraction and elemental analysis. X-ray single crystal diffraction characterization results show that the complex belongs to the triclinic crystal system, space group P1. Crystallographic parameters: a = 7.9829 (6) , b = 8.5402 (7) , c = 11.5164 9, α = 91.636 (2), β = 91.837 (2) ° and γ = 104.670 (2) ° , V = 758.61 (10) ~ 3, Z = 2.