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利用三苄基氯化锡和吗啉二硫代氨基甲酸钠反应,合成了三苄基锡吗啉二硫代氨基甲酸盐。通过元素分析、红外光谱、核磁共振氢谱和质谱对其结构进行了表征。用X-射线单晶衍射测定了该化合物的晶体结构。化合物为三斜晶系,空间群P1珔,a=0.98417(16)nm,b=1.08163(19)nm,c=1.3788(2)nm,α=72.850(3)°,β=88.895(3)°,γ=64.231(3)°,Z=2,V=1.2528(4)nm3,Dx=1.469g·cm-3,μ(MoKα)=1.204mm-1,F(000)=564,R1=0.0215,wR2=0.0531。化合物中,锡原子呈五配位畸变三角双锥构型。
Tribenzyltin morpholine dithiocarbamate was synthesized by the reaction of tribenzyltin chloride and morpholine dithiocarbamate. Its structure was characterized by elemental analysis, IR, 1H-NMR and MS. The crystal structure of this compound was determined by X-ray single crystal diffraction. The compound is triclinic with space group P1 珔, a = 0.98417 (16) nm, b = 1.08163 (19) nm, c = 1.3788 (2) nm, α = 72.850 (3) ° and β = 88.895 (3) ° = γ = 64.231 (3) ° Z = 2 V = 1.2528 (4) nm3 Dx = 1.469 g · cm -3 μ (MoKα) = 1.204 mm -1 F (000) = 564 R1 = 0.0215, wR2 = 0.0531. In the compounds, the tin atom presents a five-coordinate distorted triangular double cone configuration.