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1-D quantum calculations of reaction probabilities have been carried out for the col-linear reaction Cl+HCl (v≤3)→ClH (v＇≤3)+Cl using hyperspherical coordinates. An LEPS po-tential energy surface with a shallow well depth of -3.22 KJ/mol has been used in the calculations.The state-to-state reaction probabilities have been calculated. According to the results obtained wefound that the diagonal (v=v＇) reaction probabilities dominate over the off-diagonal (vv＇) reactionprobabilities and the largest off-diagonal reaction probabilities are smaller than 0.1. The reactionprobabilities show oscillation as a function of energy. Dynamic resonances strengthen for the potentialenergy surface with a well.
1-D quantum calculations of reaction probabilities have been carried out for the col-linear reaction Cl + HCl (v ≦ 3) → ClH (v ’≦ 3) + Cl using hyperspherical coordinates. An LEPS po- tential energy surface with a shallow well depth of -3.22 KJ / mol has been used in the calculations. state to-state reaction probabilities have been calculated. According to the results obtained wefound that the diagonal (v = v ’) reaction probabilities dominate over the off-diagonal (vv ’) reactionprobabilities and the largest off-diagonal reaction probabilities are smaller than 0.1. The reactionprobabilities show oscillation as a function of energy. Dynamic resonances strengthen for the potentialenergy surface with a well.