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以4,5-二氰基咪唑(HIMDN)为原配体运用不同的方法设计合成了三维配合物Zn(HDTIM).1.5H2O(HDTIM=4,5-di(1H-tetrazol-5-yl)-2H-imidazole),利用元素分析,X-射线单晶衍射,粉末衍射以及热重分析等手段对标题化合物进行了表征,配合物属于正交晶系,P212121空间群,晶胞参数:a=0.8643(6)nm,b=0.8885(6)nm,c=1.5450(10)nm,α=β=γ=90(1)°,结果表明配合物1在较高温度下具有良好的热稳定性。
The three-dimensional complexes Zn (HDTIM) and 1.5H2O (HDTIM = 4,5-di (1H-tetrazol-5-yl) The title compound was characterized by elemental analysis, single crystal X-ray diffraction, powder diffraction and thermogravimetric analysis. The complex belongs to the orthorhombic, P212121 space group with unit cell parameters: a = 0.8643 (6) nm, b = 0.8885 (6) nm, c = 1.5450 (10) nm and α = β = γ = 90 (1) °. The results show that the complex 1 has good thermal stability at higher temperature .