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以4-硝基邻苯二甲腈、叔丁醇、对苯二甲醛等为原料,合成不对称胺基锌酞菁(2(3)-胺基-9(10),16(17),23(24)-(叔丁氧基)锌酞菁(APC))和一种新型平面双核酞菁(9(10),9’(10’),16(17),16’(17’),23(24),23’(24’)-叔丁氧基-2(3),2’(3’)-(对苯甲亚胺基)锌酞菁(bi-TPC))。通过FT-IR、UV-Vis、1HNMR、元素分析、循环伏安等手段对APC和biTPC的结构进行表征。结果表明,与无取代酞菁相比,APC和bi-TPC Q带的最大吸收峰具有明显红移;能级与纳米Ti O2薄膜匹配,适用于制备太阳能电池。
(2) (3) -amino-9 (10), 16 (17), 4-nitrophenyldronitrile and t- (10), 16 (17), 16 ’(17’) - 23 (24) - (tert-butoxy) zinc phthalocyanine (APC) and a novel planar binuclear phthalocyanine , 23 (24), 23 ’(24’) - tert-butoxy-2 (3), 2 ’(3’) - (p -benzimido) zinc phthalocyanine (bi-TPC). The structures of APC and biTPC were characterized by FT-IR, UV-Vis, 1HNMR, elemental analysis and cyclic voltammetry. The results show that compared with unsubstituted phthalocyanine, the maximum absorption peak of APC and bi-TPC Q bands has obvious red shift; the energy level matches with the nano-Ti O2 thin film and is suitable for preparing solar cells.