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合成了1种新的尾式卟啉钴——间-[邻-(4-二乙胺基丁酰胺基)苯基]三苯基卟啉合钴(Ⅱ)配合物,测定了电子光谱、红外光谱、质谱、电子自旋波谱,研究了这种尾式卟啉钴与有机碱和双原子小分子CO、NO的轴向反应及其可逆载氧性质.
A new cobalt (Ⅱ) complex of cobalt (Ⅱ) - tris (4 - diethylaminobutylamino) phenyl] triphenylporphyrin was synthesized and its electronic spectra, Infrared spectroscopy, mass spectrometry and electron spin spectroscopy were used to investigate the axial reaction and the reversible oxygen loading of this tail-porphyrin cobalt with organic bases and diatomic small molecules CO and NO.