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Angew.Chem.Int.Ed.2015,54,5210~5213通过外部化学调控精确控制反应活性和选择性,在有机催化合成中具有重要意义.在胺基催化反应中,一般通过添加有机酸来调控反应的活性和立体选择性,但难以达到理想的开关效应.最近,郑州大学化学与分子工程学院吴养洁院士、崔秀灵教授课题组与中国科学院北京化学所罗三中研究员课题组合作,巧妙地设计了具有新颖结构的
Angew.Chem.Int.Ed.2015,54,5210 ~ 5213 The precise control of reactivity and selectivity by external chemical control is of great importance in the synthesis of organic catalysis.In amine-catalyzed reactions, it is generally controlled by the addition of organic acids Reaction activity and stereoselectivity, but it is difficult to achieve the desired switching effect.Recently, Zhengzhou University, School of Chemistry and Molecular Engineering, Professor Wu Yangjie, Cui Xiu Ling Professor and the Beijing Institute of Chemistry, Chinese Academy of Sciences Luo Sanzhong research group work together to cleverly designed Has a novel structure