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(-)-curdione,the antipode of the antitumor principle of Chinese herb Curcuma aromticaSalisb.was synthesized from(-)-carvone via oxy-Cope rearrangement.This result also confirmedthe absolute configuration of natural(+)-curdione.
(-) - curdione, the antipode of the antitumor principle of Chinese herb Curcuma aromticaSalisb. was synthesized from (-) - carvone via oxy-Cope rearrangement.This result also confirmed the absolute configuration of natural (+) - curdione.