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本文报导钕钛混合膦酸盐与三异丁基铝,给电子试剂组成络合催化剂使乙炔聚合。结果表明:该催化体系活性较高,在室温(30℃)下可制得顺式含量60％左右的聚乙炔膜,它在空气中比较稳定,经电化学掺碘后成为导电性聚乙炔膜,其室温电导率达714欧~(-1)厘米~(-1)。碘化膜可以与金属锂,高氯酸锂—碳酸丙烯酸溶液构成可充式半塑料电池,其电性能良好。
This article reports neodymium titanium mixed phosphonate and triisobutylaluminum, to form a complex catalyst for electronic reagents acetylene polymerization. The results show that the catalytic system has a high activity and can produce a polyacetylene film with a cis content of about 60% at room temperature (30 ° C). The polyacetylene film is relatively stable in the air and becomes an electrically conductive polyacetylene film after being electrochemically doped with iodine The room temperature conductivity of 714 ohm ~ (-1) cm ~ (-1). Iodized film with lithium metal, lithium perchlorate - carbonated acrylic acid composition rechargeable semi-plastic batteries, the electrical performance is good.