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Its meaningful to discover the general correlation between three major industries and carbon emissions in China,and the differences of regions.In this paper,we use energy consumption data from 2005-2012 to estimate approximate carbon emissions in 27 provinces,and introduce the indicator of carbon-emergy coefficient to counteract error,which is different from former researches.Then we calculate the grey relation between 27 provinces and three major industries.Results reveal that the secondary industry has higher relation with carbon emissions in 15 provinces.Results also talk about the regional characteristic of carbon emissions,which help policy makers discover determine the preference of limiting carbon emissions.