迄今为止VO2一共有6种晶型,包括VO2(A),VO2(B),VO2(C),VO2(M)和VO2(R)等．尽管目前发展了众多不同的技术方法制备VO2薄膜,但是很少有制备VO2超细粉末的简便方法。本文结合作者的研究工作,综述了二氧化钒粉末的合成技术,如:传统的固相方法、热解法、软化学方法、水热法、溶胶-凝胶法和激光诱导气相沉积法等,比较了各种技术的优缺点并提出了将来有关合成技术可能的研究方向。 So far there are 6 kinds of VO2 crystal forms, including VO2 (A), VO2 (B), VO2 (C), VO2 (M) and VO2 (R) and so on. Although many different techniques have been developed for the preparation of VO2 thin films, there are few easy ways to prepare ultra-fine VO2 powders. In this paper, the synthesis of vanadium dioxide powders, such as the traditional solid-phase method, pyrolysis method, soft chemical method, hydrothermal method, sol-gel method and laser induced vapor deposition method, The advantages and disadvantages of various technologies are compared and future research directions on the synthesis technology are proposed.