In this paper, we introduced a novel method to prepare the few-layer nitrogen-doped graphene (FNG) from expandable graphite with melamine. The super-capacitive properties of FNG were thoroughly characterized by a three-electrode system, and the results showed the FNG electrode achieved a specific capacitanceashighas83.8 mF/cm2togetherwithexcellentcyclingstability.Thismethodcouldbeanovel approach to combine the pseudo-capacitors and electric double layer capacitors.