With excellent color purity (full-width half maximum (FWHM)＜40 nm) and high quantum yield, multi-resonance (MR) molecules can harvest both singlet and triplet excitons for highly efficient narrowband organic light-emitting diodes (OLEDs) owing to their thermally activated delayed fluorescence (TADF) nature. However, the highly rigid molecular skeleton with the oppositely positioned boron and nitrogen in generating MR effects results in the intrinsic difficulties in the solution-processing of MR-OLEDs. Here, we demonstrate a facile strategy to increase the solubility, enhance the efficiencies and modulate emission color of MR-TADF molecules by extending aromatic rings and introducing tert-butyls into the MR backbone. Two MR-TADF emitters with smaller singlet-triplet splitting energies (△EST) and larger oscillator strengths were prepared conveniently, and the solution-processed MR-OLEDs were fabricated for the first time, exhibiting efficient bluish-green electroluminescence with narrow FWHM of 32 nm and external quantum efficiency of 16.3%, which are even comparable to the state-of-the-art performances of the vacuum-evaporated devices. These results prove the feasibility of designing efficient solution-processible MR molecules, offering important clues in developing high-performance solution-processed MR-OLEDs with high efficiency and color purity.