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  5. Kinetics and mechanism of the reaction between thiourea and iodate in unbuffered medium

Kinetics and mechanism of the reaction between thiourea and iodate in unbuffered medium

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：zlq
【摘 要】
：
The reaction between iodate and thiourea has been studied in an unbuffered acidic medium. In excess iodate the reaction shows not only oligooscillations in pH,
【作 者】
：
WANG Shun LIN Juanjuan CHEN Fa 
【机 构】
：
DepartmentofChemistryandMaterialScience,CollegeofChemicalEngineering
【出 处】
：
中国科学：化学英文版
【发表日期】
：
2004年6期
【关键词】
：
oligooscillations pH dynamics thiourea iodate COMPLEX REACTION mechanism dy 
【基金项目】
：
This work was supported by the National Natural Science Foundation of China (Grant Nos. 20103010 and 20073039).
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The reaction between iodate and thiourea has been studied in an unbuffered acidic medium. In excess iodate the reaction shows not only oligooscillations in pH, Pt potential and the concentration of iodide ion, [I-], but also an initial induction period wh
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