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研究空气稳定性好的聚乙炔(PA)导电材料,是目前国际上急待解决的难题。我们从聚氯乙烯出发制备了在空气中稳定的硫化类聚乙炔材料(SLPA),并对其结构性能进行了表征,从量子化学角度研究了硫化对PA电子性质的影响。
Studying polyacetylene (PA) conductive material with good air stability is an urgent problem to be solved in the world at present. We prepared a stable sulfidic polyacetylene material (SLPA) from polyvinyl chloride (PVC) and characterized its structural properties. The effect of sulfidation on the electronic properties of PA was studied from the perspective of quantum chemistry.