由 Co2 (CO) 8与 3个含硫、磷杂原子的有机前配体反应 ,得到两个四核和一个六核含硫、磷原子配位分子片的新颖钴羰基簇合衍生物 .通过元素分析、1HNMR和 MS等谱学表征 ,确定它们的化学组成如下 :Co4 (μ3 -S)〔P(S) (OCH3 ) 2 〕2 (CO) 9( )、Co4 (μ,η2 -S2 )〔P(O-i-C3 H7) 2 〕2 (CO) 10 ( )和 Co6(μ3 -S) 2 (μ-SP ) (μ6,η3 -SP ) (μ-CO) (CO) 10 ( ) .对它们可能的立体结构进行了推测 Co2 (CO) 8 reacted with three organic ligands containing sulfur and phosphorus heteroatoms to obtain novel cobalt carbonyl derivatives of two tetranuclear and six hexanuclear sulfur and phosphorus coordination molecules. Elemental analysis, 1HNMR and MS spectra showed that the chemical compositions were as follows: Co4 (μ3 -S) [P (S) (OCH3) 2] 2 (CO) 9 P (Oi-C3 H7) 2] 2 (CO) 10 () and Co6 (μ3 -S) 2 (μ-SP) Their possible three-dimensional structure was speculated