论文部分内容阅读
The oxidation of para‐xylene to terephthalic acid has been commercialised as the AMOCO process(Co/Mn/Br) that uses a homogeneous catalyst of cobalt and manganese together with a corrosive bromide compound as a promoter. This process is conducted in acidic medium at a high tempera‐ture(175–225 °C). Concerns over environmental and safety issues have driven studies to find mild‐er oxidation reactions of para‐xylene. This review discussed past and current progress in the oxida‐tion of para‐xylene process. The discussion concentrates on the approach of green chemistry in‐cluding(1) using heterogeneous catalysts with promising high selectivity and mild reaction condi‐tion,(2) application of carbon dioxide as a co‐oxidant, and(3) application of alternative promoters. The optimisation of para‐xylene oxidation was also outlined.
The oxidation of para-xylene to terephthalic acid has been commercialized as the AMOCO process (Co / Mn / Br) that uses a homogeneous catalyst of cobalt and manganese together with a corrosive bromide compound as a promoter. This process is conducted in an acidic medium at Concerns over environmental and safety issues have driven studies to find mild-er oxidation reactions of para-xylene. This review discusses past and current progress in the oxida- tion of para-xylene process. The discussion concentrates on the approach of green chemistry in-cluding (1) using heterogeneous catalysts with promising high selectivity and mild reaction condi- tion, (2) application of carbon dioxide as a co-oxidant, and (3) application of alternative promoters. The optimization of para-xylene oxidation was also outlined.