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本文研究了运用四氧化二氮硝化对苯二醛二肟,经过对——双(二硝基甲基)苯的钾盐,合成对——双(三硝基甲基)苯的两段硝化法。在合成对——双(二硝基甲基)苯上,扩大了Ponzio反应的应用范围,比1969年发表的[1]Rowley和Frankel的方法,改变了合成路线,显著提高了产率。在合成对——双(三硝基甲基)苯上,把和向苯环上引入一个三硝基甲基的方法,推广到苯环上引入两个三硝基甲基,合成了这个新化合物,是这种三硝基化方法的一个发展。对苯二醛二肟与大过量的四氧化二氮的反应,虽然主要产物是偕二硝基化合物,次要产物是对苯二醛,但是确实伴有对——双(三硝基甲基)苯的生成,这就为在某些情况下从两段硝化法进展到一段硝化法,开辟了可能的途径。
In this paper, we studied the nitration of terephthalic dialdehyde with dinitrogen tetra-nitrosation to the two-stage nitration of p-bis (trinitromethyl) benzene via the potassium salt of p-bis law. On the synthesis of p-bis (dinitromethyl) benzene, the scope of Ponzio reaction was broadened. Compared with [1] Rowley and Frankel published in 1969, the synthesis route was changed and the yield was significantly improved. On the synthesis of p-bis (trinitromethyl) benzene, and the introduction of a trinitrotoluene to the benzene ring on the way to promote the introduction of two trinitrotoluene on the benzene ring, the synthesis of this new Compounds, is a development of this method of trinitration. The reaction of terephthalaldehyde dioxime with a large excess of dinitrogen tetraoxide, although the major product is a geminal dinitro compound and the secondary product is terephthalaldehyde, does, however, do with p-bis (trinitromethyl ) Benzene generated, which opened up a possible way for the progress of nitrification from two nitrification to nitrification in some cases.