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自七十年代初,S.Eksborg建立离子对色谱法以来,很快被用于有机磺酸的分析。例如:1976年,J.H.Knox 采用十六烷基季铵盐作为反离子,在C_2柱上分离了含有1～3个-SO_3H基团的染料中间体;1983年,A.Kraslawski等采用磷酸四丁基铵作为反离子,在C_(18)柱上分离2,1-萘胺磺酸在磺化过程中的一系列产物;同年,P.Jandera等采用硫酸季铵盐作为反离子,在C_(18)或C_8柱上分离了34种萘磺酸和蒽醌磺酸等染料中间体。
Since the early seventies, S.Eksborg has been rapidly used for the analysis of organic sulfonic acids since the establishment of ion-pair chromatography. For example, JHKnox used cetyl quaternary ammonium salt as a counterion in 1976, and isolated a dye intermediate containing 1 to 3 -SO_3H groups on a C_2 column. In 1983, A. Kraslawski et al. In the same year, P.Jandera et al. Used quaternary ammonium sulfate as a counter ion to react with C_ (18) column on the C_ (18) column to separate a series of products of sulfonation of 2,1- 18) or C_8 column separated 34 naphthalene sulfonic acid and anthraquinone sulfonic acid and other dye intermediates.