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本文研究了两相催化体系中，在ＣＴＡＢ（Ｃ＿（１６）Ｈ＿（３３）ＮＭｅ＿３Ｂｒ）存在下，水溶性铑－膦配合物ＲｈＣｌ（ＣＯ）（ＴＰＰＴＳ）＿２对１－己烯氢甲酰化反应的催化性能，详细考察了反应温度、压力、膦／铑比等对催化活性的影响。结果表明，在１．０ＭＰａ恒压下，反应温度１００℃，膦／铑摩尔比为１６，Ｈ＿２：ＣＯ＝１：１的条件下，１－己烯氢甲酰化的转化频率（ＴＯＦ）可达到３９．８ｍｉｎ￣（－１）。在此反应条件下，有机相和水相容易分离，铑－膦配合物流失到有机相中的量极小。
In this paper, we studied the hydroformylation of 1-hexene with water-soluble rhodium-phosphine complex (RhPc) (TPPTS) 2 in the presence of CTAB (C_ (16) H_ (33) NMe_3Br) The effects of reaction temperature, pressure, phosphine / rhodium ratio on the catalytic activity were investigated in detail. The results showed that the conversion frequency (TOF) of 1-hexene hydroformylation under the condition of constant pressure of 1.0MPa, reaction temperature of 100 ℃, molar ratio of phosphine to rhodium of 16 and H 2: CO = 1: 1 Reaching 39.8 min ~ (-1). Under this reaction conditions, the organic and aqueous phases are easily separated and the amount of rhodium-phosphine complex lost to the organic phase is extremely small.