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通过环戊二烯基-二羰基-三苯基膦合铁的氯化物(1)与十四氢十一硼烷阴离子反应,得到新的环戊二烯基-二羰基一三苯基膦合铁的十四氢十一硼烷化合物(Ⅱ).用元素分析、红外和紫外光谱、~1H 和~(11)B 核磁共振谱以及摩尔电导率等表征了Ⅱ.~(11)B NMR 的数据表明Ⅱ中存在着三组不同的硼原子。
The reaction of the chloride (1) of cyclopentadienyl-dicarbonyl-triphenylphosphine iron with the tetradecahydroundecaborane anion gave the new cyclopentadienyl-dicarbonyl-triphenylphosphine Iron (Ⅱ) Tetrahydrunoborane Compound (Ⅱ). Characterization of Ⅱ. ~ (11) B NMR spectra by elemental analysis, IR and UV spectra, ~ 1H and ~ (11) B nuclear magnetic resonance spectra and molar conductivity The data show that there are three different groups of boron atoms in II.