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用具有抗癌活性的(Z) - 1-[2 - (二卤化苯基锡基乙烯基)] -环辛醇与含氮的双齿配体作用,合成了一系列新的有机锡络合物,通过IR,1HNMR,元素分析和摩尔电导值的测定对其结构、性质进行了表征,特别对有机锡化合物分子内O→Sn配位键的离解与配体中烯基质子化学位移(1HNMR)的相关性进行了讨论
A series of new organotin complexes have been synthesized by the action of (Z) -1- [2 - (phenyltindiyl) halocyclooctanol with anticancer activity and nitrogenous bidentate ligands Their structures and properties were characterized by IR, 1HNMR, elemental analysis and molar conductance measurements. In particular, the dissociation of the O → Sn coordination bond in the organotin compound and the proton chemical shift in the ligand (1HNMR ) The relevance of the discussion