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1.合成八种氧鈾的Schiff碱新型內絡合物,由化学分析証明皆合两分手硝酸而鈾的配位数为八。 2.用热天平研究所合成的絡合物的热分解,証明硝酸分子确实位于絡合物的內界。 3.测量所合成的八种絡合物的克分子电导度,証明它們与三离子盐类的电导度相近,并指出在絡合物中硝酸的氫有可能形成氫鍵。 4.已测定所合成絡合物在乙醇中的溶解度。
1. Synthesis of eight new uranium Schiff base complexes of uranium, chemical analysis showed that both biphasic nitric acid and uranium coordination number of eight. 2. The thermal decomposition of the synthesized complex thermal decomposition, to prove that nitric acid molecules are indeed located in the complex interior. 3. The molecular conductance of the eight complexes synthesized was measured and their conductivity was proved to be similar to that of the three-ion salt. It was also pointed out that the hydrogen of the nitric acid in the complex may form hydrogen bonds. 4. The solubility of the synthesized complex in ethanol has been determined.