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A new type of organosilicon reactive intermediate,α-furylphenylsilylene was gene-rated from 2-(α-furyl)-2-phenylhexamethyltrisilane.When α-furylphenylsilylene reacted with2,3-dimethyl-1,3-butadiene,the corresponding addition and insertion products were obtained.Theintermediate silirane derivative from the reaction of α-furylphenylsilylene with cyclohexene was ring-opened by methanol to give α-furylphenyl cyclohexylmethoxylsilane.
A new type of organosilicon reactive intermediate, α-furylphenylsilylene was gene-rated from 2- (α-furyl) -2-phenylhexamethyltrisilane .When α-furylphenylsilylene reacted with 2,3-dimethyl-1,3-butadiene, the respective addition and insertion products were obtained. The intermediate silirane derivative from the reaction of α-furylphenylsilylene with cyclohexene was ring-opened by methanol to give α-furylphenyl cyclohexylmethoxylsilane.