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By means of Miedema formation enthalpy model with Toop model, the excess free-energy, enthalpies of formation, excess entropies and activity values of all components of Mg-Al-Y ternary alloy were calculated with computer programming. The experimental results show that enthalpies of formation, excess freeenergy and excess entropies of the ternary alloy are negative in the whole content range, the minimum values at 1 123 K are all obtained at x Al=55%, x Y=45%, x Mg=0%, which are-37.969, –30.961 kJ/mol and-6.24 J/(mol·k) respectively. Activity curves show that the activity values of Al and Y in Mg-Al-Y ternary alloy rapidly decrease with the decrease of molar fraction, the values of which are very small when the molar fraction decreases to 0.4. It means that there is a strong interaction between Al and Y and stable compounds can be form in the Mg-Al-Y ternary alloy system.
By means of Miedema formation enthalpy model with Toop model, the excess free-energy, enthalpies of formation, excess entropies and activity values of all components of Mg-Al-Y ternary alloy were calculated with computer programming. The experimental results show that enthalpies of formation, excess free energy and excess entropies of the ternary alloy are negative in the whole content range, the minimum values at 1 123 K are all obtained at x Al = 55%, x Y = 45%, x Mg = 0%, which are -37.969, -30.961 kJ / mol and-6.24 J / (mol · k) respectively. Activity curves show that the activity values of Al and Y in Mg-Al-Y ternary alloy rapidly decrease with the decrease of molar fraction, the values of which are very small when the molar fraction decreases to 0.4. It means that there is a strong interaction between Al and Y and stable compounds can be in the Mg-Al-Y ternary alloy system.