导电高分子复合材料(Conductive Polymer Composites,CPCs)研究的重点和热点之一是如何控制导电粒子的分布,有效降低CPCs逾渗值,提高CPCs综合性能,其中具有隔离结构的CPCs因能大大降低复合材料的逾渗值而受到研究者的广泛关注。本文综述了制备隔离结构CPCs的方法,包括机械共混法、溶液共混法、乳液法等,分析了此类材料具有较低逾渗值的机理,总结了此类材料对温度、溶剂等外场的响应规律。根据复合材料微观结构指出提高此类材料力学性能是推进此类材料应用的关键。 Conductive Polymer Composites (CPCs) one of the research focuses and hot spots is how to control the distribution of conductive particles, effectively reduce the percolation of CPCs and improve the overall performance of CPCs, including the isolation structure of CPCs can greatly reduce the composite Material percolation value by researchers wide attention. In this paper, the methods of preparation of CPCs with isolation structure are reviewed, including mechanical blending, solution blending and emulsion methods. The mechanism of low percolation value of these materials is analyzed. The effects of such materials on temperature, solvent, The response law. According to the composite microstructure, it is pointed out that improving the mechanical properties of such materials is the key to promote the application of such materials.