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The hydrothermal reaction of Zn(NO).4HO, cyclohexane-1,2,3,4,5,6-hexacarboxylic acid hydrate (HL: a,e,a,e,a,e) and 2,2'-bpy yielded a new coordination polymer [Zn(HL and Z=2. The structure is a three-dimensional supramolecular network based on linear coordination chains through π-π stacking and hydrogen bonding interactions. The confromation of the starting ligand HL. The complex emits strong luminescence at room temperature.