论文部分内容阅读
本文用分子轨道理论讨论有机反应的立体选择性问题,应用包含σ-π相互作用的HMO法并考虑了电子密度的影响,来说明加成反应、消除反应和S_N2′反应的立体选择性问题。理论上的推测与许多实验事实相符合。
In this paper, the molecular orbital theory is used to discuss the stereoselectivity of organic reactions. The HMO method with σ-π interaction and the effect of electron density are considered to explain the stereoselectivity of the reaction and the elimination of S_N2 ’reactions. Theoretical inference conforms to many experimental facts.