Preparation of large-size Al2O3/GdAlO3/ZrO2 ternary eutectic ceramic rod by laser directed energy de

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Laser 3D printing based on melt growth has great potential in rapid preparation of Al2O3-based eutectic ceramics.In this work,large-scale Al2O3/GdAlO3/ZrO2 ternary eutectic ceramic rod with diameter of 4-5 mm and height higher than 250 mm was additively manufactured by laser directed energy deposition.Especially,heat treatment was applied to eliminate the microstructure heterogeneity in the as-deposited eutectic ceramic,and the microstructure homogenization mechanism was studied in depth.The results indicate that colonies and banded structures completely disappear after the heat treatment,producing a homogeneous network eutectic structure.The microstructure homogenization is revealed to experience three stages of discontinuous coarsening,continuous coarsening and microstructure coalescence.Addi-tionally,it is found that the eutectic spacing linearly increases with the heat treatment time,meaning that the coarsening behavior of the laser 3D-printed Al2O3/GdAlO3/ZrO2 eutectic ceramic satisfies well with the Graham-Kraft model.
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