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本文选取苯基乙酰甲基亚砜(C6H5SOCH2COCH3)作为配体与碱土金属(钙、锶)的高氯酸盐反应得到配合物的单晶,对它们进行了元素分析及红外光谱表征,它们的化学式为[ML6](ClO4)2(M=Ca、Sr;L=C6H5SOCH2COCH3)。并用X-ray单晶衍射法测定了钙、锶配合物的晶体结构。
In this paper, phenylacetyl methyl sulfoxide (C6H5SOCH2COCH3) was selected as the ligand to react with perchlorate of alkaline earth metal (calcium and strontium) to obtain the single crystal of the complex, and their elemental analysis and infrared spectrum characterization were carried out. Their chemical formulas [ML6] (ClO4) 2 (M = Ca, Sr; L = C6H5SOCH2COCH3). The crystal structure of calcium and strontium complexes was determined by X-ray single crystal diffraction.