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在相对论多组态Dirac_Fock理论方法基础上 ,通过系统考虑电子关联效应和由于内壳层电子激发而导致的电子自旋_轨道波函数的弛豫效应 ,详细研究了CsⅣ离子的 4d内壳层电子激发组态 4d95s2 5p5、辐射末态 4d1 0 5s2 5p4 及Auger末态 4d1 0 5s2 5p3和 4d1 0 5s1 5p4 的能级结构及各种可能的辐射和Auger衰变过程 .获得了与已有的实验结果和相关的半经验准相对论组态相互作用计算结果相符的辐射跃迁能、振子强度以及线宽 ,预言了 4d95s2 5p5态的以Auger衰变为主的Auger电子谱的特性
Based on the theory of relativistic multi-configuration Dirac_Fock theory, by systematically considering the electron correlation effect and the relaxation effect of the electron spin-orbit wave function due to the electron excitation in the inner shell, the inner shell electrons The energy level structure of 4d95s2 5p5, 4d105s2 5p4 and 4d1 05s2 5p3 and 4d1 05s1 5p4 in the final state of radiation and all kinds of possible radiation and Auger decay processes are excited, and the results obtained with the existing experimental results and The correlation of the semi-empirical relative theory of configuration interaction with the calculated radiation transition energy, oscillator strength and line width, predicts the 4d95s2 5p5 Auger decay-dominated Auger electron spectroscopy properties