1IntroductionPolyanilines are one of the promising electrically conducting π-conjugated polymers with chemical stability. In recent year, there has been increased interest in chiral induction of polyanilines because of their potential use in diverse areas. Chiral polyaniline has been reported to be formed only by the chiral acid dopant[1]. In our previous papers, complexation of polyanilines or their oligomers with transition metals modulates the redox properties of the quinonediimine unit, which is related to the catalytic function in the oxidation reaction[2].The controlled complexation with palladium(Ⅱ) compounds has been achieved to afford the cross-linked network conjugated complexes, in which the quinonediimine moieties serve as bridging coordination sites[3].Another hybrid system consisting of π-conjugated polymer and transition metal is also described.