Two New Steroidal Glycosides from Fermented Leaves of Agave americana

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Two new spirostanol glycosides named agamenoside A and B, were isolated from the fcrmcnted leaves of Agave americana. Their structures were elucidated as (23S, 25R)-5α-spirostan-3β, 6α, 23-triol 3-O-α-L-rhamnopyranosyl-(1→3)- β-D-glucopyranosyl-(l→2)-[β-D-xylopyranosyl-( 1 →3)]-β-D-glucopyranosyl-( l →4)-β-D-galactopyranoside (1) and (25R)-5α-spiro stan-3β, 6α-diol 3-O-β-D-glucopyranosyl-(l→2)-[ β-D-xylopyranosyl-(l→3)]- β-D-glucopyra nosyl-(1→4)- β-D-galactopyranoside (2) by a combination of chemical and spectral methods.
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