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IR and NMR spectra of novel bionics insecticide—C_5NS_4O_6H_(12)Na·H_2O have been studied. The molecular and crystal structures of the compound also have been determined. The compound crystallizes in the monoclinic space group C_(2h)~5, - P2_1/n with α= 8.0972. (9) , b =16.262(4), c = 10.370(3), β= 94.26(2)° and z = 4.The result shows that N atom in this compound captures a proton to form HN~+ group, Na~+ is in statistical disorder. Therefore, the structural formula of tho compound is (CH_3)_2HN~+—CH(CH_2S_2O_3~-)_2·1/2 (Na~+)_2·H_2O.
IR and NMR spectra of novel bionics insecticide-C_5NS_4O_6H_ (12) Na · H_2O have been studied. The molecular and crystal structures of the compound have also been determined. The compound crystallizes in the monoclinic space group C_ (2h) ~ 5, - P2_1 / n with α = 8.0972 (9), b = 16.262 (4), c = 10.370 (3), β = 94.26 (2) ° and z = 4. The result shows that N atom in this compound captures a proton to The structural formula of tho compound is (CH_3) _2HN ~ + -CH (CH_2S_2O_3 ~ -) _2 · 1/2 (Na ~ +) _2.H_2O.