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本文应用低分辨电子轰击源质谱,化学电离质谱,高分辨精确质量测量,亚稳分析和不同取代基衍生物方法,研究了十二种硫逐磷酸酯和二硫代磷酸酯的质谱。根据所得数据,推断并讨论了这些化合物的断裂机理及特征离子的结构。
In this paper, low-resolution electron impact mass spectrometry, chemical ionization mass spectrometry, high-resolution accurate mass measurement, metastable analysis and different substituent derivatives method, the twelve kinds of phosphorothioate and dithiophosphate mass spectrometry. Based on the obtained data, the fracture mechanism of these compounds and the structure of the characteristic ions are deduced and discussed.