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It is a key step for reducing waste generation in chemical processes to design op-timal reaction paths. In this paper, methods of waste minimization for reaction path synthesis problems are proposed to realize eco-industrial production mode with minimum waste emission. A new conception of simple stoichiometric reaction is presented for reaction path synthesis problem. All simple stoichiometric reactions can be obtained by mathematical transformation for atom matrix of a reaction system. Based on the conception, a two-tier optimization method for complex reaction path synthesis problems is addressed. The first step is to determine the eco-nomic optimal overall reactions, and the second step to decompose each overall reaction into several sub-reactions and find out the best thermodynamic feasible reaction path. Further, a method of reaction path synthesis with waste closed-cycle is proposed based on simple stoichiometric reactions for achieving zero waste emission to poly-generation problem of multi-products. Case studies show that the proposed methods can efficiently solve practical re-action path synthesis problems.
It is a key step for reducing waste generation in chemical processes to design op-timal reaction paths. In this paper, methods of waste minimization for reaction path synthesis problems are to now eco-industrial production mode with minimum waste emission. A new conception of simple stoichiometric reaction for presented reaction path synthesis problem. All simple stoichiometric reactions can be obtained by mathematical transformation for atom matrix of a reaction system. Based on the conception, a two-tier optimization method for complex reaction path synthesis problems is addressed. The first step is to determine the eco-nomic optimal overall reactions, and the second step to decompose each overall reaction into several sub-reactions and find out the best thermodynamic feasible reaction path. Further, a method of reaction path synthesis with waste closed- cycle is proposed based on simple stoichiometric reactions for achieving zero waste emission to poly-generation prob lem of multi-products. Case studies show that the proposed methods can indeed solve practical re-action path synthesis problems.