【摘 要】
：
Hydrothermal reaction of 3-aminopyridine, NaSCN and cadmium cation led to the formation of complex [Cd(3-ampy)(NCS)2]n 1 (3-aminopyridine = 3-ampy), and its cry
【机 构】
：
Department of Chemistry,State Key Laboratory of Structural Chemistry
论文部分内容阅读
Hydrothermal reaction of 3-aminopyridine, NaSCN and cadmium cation led to the formation of complex [Cd(3-ampy)(NCS)2]n 1 (3-aminopyridine = 3-ampy), and its crystal structure was determined by X-ray diffraction analysis. The crystal data for compound 1: C7H6N4S2Cd, orthorhombic Fdd2, Mr = 322.68, Z = 16, a = 26.884(4), b = 27.445(3), c = 5.8671(7)(A), V = 4329.0(10)(A)3, Dc = 1.974 g/cm3, μ = 2.368 mm-1, F(000) = 2496, R = 0.0203 and wR = 0.0491 for 2347 observed reflections with I > 2σ(I), and absolute structure parameter is 0.00(3). X-ray diffraction reveals that the compound consists of interesting two-dimensional wave sheet structure. The photoluminescence spectrum and interesting second-order nonlinear optical (NLO) property for compound 1 have also been studied.
其他文献
A novel cadmium(Ⅱ) coordination polymer {[Cd(1,5-nds)(Him)2(H2O)]·2H2O}n (1,5-nds = naphthalene-1,5-disulfonate and Him = imidazole) was synthesized based on
A novel application of horseradish peroxidase (HRP) in the oxidation of alcohol ethoxylate to alkylether carboxylie acid in the present of H2O2 was reported in
Two mononuclear metal-organic complexes, [Co(Hmpdc)2(H2O)4]·4H2O 1 and [Ni(Hfmpdc)2(H2O)4]·6H2O 2, were prepared from 2,6-dimethylpyridine-3,5-dicarboxylic ac
The micron-sized mierospheres with superparamagnetic property were synthesized with vinyl acetate and divinylbenzene by microsuspension polymerization. After th
The mixture of cesium hydroxide and terminal alkynes in dry DMF in the presence of 4(A°), molecular sieves was stirred for 3.0 h at room temperature under N2,
A novel degradable pH-sensitive hydrogel with pendent carboxyl groups was designed and synthesized from ethylenediami-netetraacetic dianhydride (EDTAh) and buta
Chloroperoxidase (CPO) was immobilized by konjac glucornannan (KGM) on the 1-butyl-3-methyl imidazolium tetrafluor-oborate [BMIM][BF4]/Nafion modified glassy ca
Three new functional group containing borazine derivatives, 2,4,6-tri(allylamino)borazine, 2,4,6-tri(3-ethynylanilino)borazine, and 2,4,6-tri(4-propargyl oxyani
Fe(HSO4)3 has been used as an efficient and reeyclable catalyst for the one-pot synthesis of 14-aryl- or alkyl-14H-dibenzo[a,j]xanthene derivatives by the react
1N-Acetyl-3-(2,4-dichloro-5-fluoro-phenyl)-5-(p-methyl-phenyl)-2-pyrazoline has been synthesized and characterized by elemental analysis, IR, UV-Vis and X-ray s