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利用同步辐射光电高质谱法对间硝基本胶(C6H6N2O2)进行了研究;测得了其电离势IP(C6H6N2O2)为966±0.05ev,以及一些碎片离子出现势AP,计算出了离解能D0(N2O-C6H6N+)和离子生成焓△Hf(C6H6N+).给出了间硝基苯胜的同步辐射光电离质谱图,并对主要碎片离子的产生过程进行了初步分析.
The synchrotron radiation photoelectron high mass spectrometry (GC-MS) was used to study the intergranular basic gum (C6H6N2O2). The ionization potential IP (C6H6N2O2) was found to be 966 ± 0.05ev and some APs appeared. The dissociation energy D0 -C6H6N +) and the ion formation enthalpy △ Hf (C6H6N +). The synchrotron radiation photoionization (MS) spectra of m-nitrophenylsulfonic acid were given and the generation of major fragment ions was analyzed.