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本文在超临界流体色谱保留值方程(1)的基础上,用文献中同系物的数据考察了方lnk’=a+b/T-c·ρm/T+d·ρm~(2(?)) (1)程中的各参数,并在此方程的基础上解释了定柱压下lnk’与1/T图中的最大值效应
Based on the retention equation (1) of the supercritical fluid chromatography and the data of the homologues in the literatures, we investigate the effects of lnk ’= a + b / Tc · ρm / T + d · ρm ~ 1) process, and based on this equation, we explain the maximum effect of lnk ’and 1 / T in the fixed column