我们报道过四氯化碳-含氧化合物二元系固液相平衡,本文报道四氯化碳-含氮化合物二元系固液相平衡.四氯化碳与苯可形成电荷转移配合物,苯环上连结斥电子基团,苯环的电荷密度加强,更有利于配合物的形成,苯环上连结吸电子基团,苯环电荷密度减弱,不利于配合物的形成.另外,四氯化碳与氮原子也发生电荷转移作用,四氯化碳与N-甲基吡咯形成固体化合物是一个例子.氮原子若连结在苯环上,能否与四氯化碳形成固体化合物呢?为此,本文测定了四氯化碳-苯胺/N,N-二甲基苯胺的二元固液相平衡. We reported the CFC-B binary system solid-liquid equilibrium, reported here CTC-B binary system solid-liquid equilibrium. CTC and benzene can form charge-transfer complexes, The benzene ring is repulsed electron group, the charge density of the benzene ring is strengthened, more conducive to the formation of complexes, benzene ring electron-withdrawing group, benzene ring charge density weakened, is not conducive to the formation of complexes .In addition, tetrachloro Carbon and nitrogen atoms also charge transfer occurs, carbon tetrachloride and N-methyl pyrrole to form a solid compound is an example. If the nitrogen atom is attached to the benzene ring, with carbon tetrachloride can form a solid compound? In this paper, binary solid-liquid equilibrium of carbon tetrachloride-aniline / N, N-dimethylaniline was determined.