Ultrathin porous graphitic carbon nanosheets activated by alkali metal salts for high power density

来源 :稀有金属(英文版) | 被引量 : 0次 | 上传用户:redmend
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Graphitic carbons with reasonable pore volume and appropriate graphitization degree can provide efficient Li+/electrolyte-transfer channels and ameliorate the slug-gish dynamic behavior of battery-type carbon negative electrode in lithium-ion capacitors(LICs).In this work,onion-like graphitic carbon materials are obtained by using carbon quantum dots as precursors after sintering,and the effects of alkali metal salts on the structure,morphology and performance of the samples are focused.The results show that alkali metal salts as activator can etch graphitic carbons,and the specific surface area and pore size dis-tribution are intimately related to the description of the alkali metal salt.Moreover,it also affects the graphitization degree of the materials.The porous graphitic carbons(S-GCs)obtained by NaCl activation exhibit high specific surface area(77.14 m2.g-1)and appropriate graphitization degree.It is expectable that the electrochemical perfor-mance for lithium-ions storage can be largely promoted by the smart combination of catalytic graphitization and pores-creating strategy.High-performance LICs(S-GCs//AC LICs)are achieved with high energy density of 92 Wh?kg-1 and superior rate capability(66.3 Wh?kg-1 at 10 A?g-1)together with the power density as high as 10020.2 W?kg-1.
其他文献
北衙金矿是一个大型金多金属矿,已有的研究表明北衙金矿中银主要赋存于氧化锰矿物中,而赋存于氧化带铁锰矿石中的银分离提取困难,被称为难浸的“顽银”.本研究是从矿区上部氧
钛和锆及其合金具有强度高和良好的耐腐蚀性能,在多个工业领域的应用研究发展迅速.通过爆炸焊接方法制备了锆-钛复合板,并对复合板进行钨极惰性气体保护焊焊接制备对接焊接接