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A metal-organic coordination polymer [Co2(cbba)4(bix)2]n(Hcbba = 2-(4’-chlorine-benzoyl)-benzoic acid,bix = 1,4-bis(imidazol-1-ylmethyl)-benzene) 1 has been hydrothermally synthesized and characterized by elemental analysis,IR,TG,and single-crystal X-ray diffraction.Pink crystals crystallize in the monoclinic system,space group P21/n with a = 21.148(4),b = 15.728(3),c = 23.879(4) ,β = 102.148(3)°,V = 7764(2)3,C316H232Cl15Co8N32O48,Mr = 6248.53,Dc = 1.336 g/cm3,F(000) = 3207,Z = 1,μ(MoKα) = 0.621 mm-1,the final R = 0.0567 and wR = 0.1280 for 8510 observed reflections(I > 2σ(I)).The structure of 1 exhibits a one-dimensional chain-like structure.
A metal-organic coordination polymer [Co2 (cbba) 4 (bix) 2] n (Hcbba = 2- (4’-chlorine- benzoyl) -benzoic acid, bix = benzene) 1 has been hydrothermally synthesized and characterized by elemental analysis, IR, TG, and single-crystal X-ray diffraction. Pink crystals crystallize in the monoclinic system, space group P21 / n with a = 21.148 (4), b = 15.728 C = 23.879 (4) β, β = 102.148 (3) °, V = 7764 (2) 3, C316H232Cl15Co8N32O48, Mr = 6248.53, Dc = 1.336 g / cm3, F = 1, μ (MoKα) = 0.621 mm -1, the final R = 0.0567 and wR = 0.1280 for 8510 observed reflections (I> 2σ (I)). The structure of 1 exhibits a one-dimensional chain-