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In this work,a multi-core-shell-structured LiFePO4@Na3V2(PO4)3@C (LFP@NVP@C) composite was successfully designed and prepared to address inferior low-temperature performance of LiFePO4 cathode for lithium-ion batteries.Transmission electron microscopy (TEM) confirms the inner NVP and outer carbon layers coexisted on the surface of LFP particle.When evaluated at low-temperature operation,LFP@NVP@C composite exhibits an evidently enhanced electrochemical performance in term of higher capacity and lower polarization,compared with LFP@C.Even at-10 ℃ with 0.5C,LFP@NVP@C delivers a discharge capacity of ca.96.9 mAh·g-1 and discharge voltage of ca.3.3 V,which is attributed to the beneficial contribution of NVP coating.NASICON-structured NVP with an open framework for readily insertion/desertion of Li+ will effectively reduce the polarization for the electrochemical reactions of the designed LFP@NVP@C composite.