【摘 要】
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N-2-Thiazolylacrylamide (NTA) was polymerized by a radical route to obtain the polymer in good yield. The polymer with a pendent heterocyclic group is soluble i
【机 构】
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Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027
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N-2-Thiazolylacrylamide (NTA) was polymerized by a radical route to obtain the polymer in good yield. The polymer with a pendent heterocyclic group is soluble in common organic solvents, which allow to prepare the corresponding metal complexes with higher loads easily. FTIR, 1H NMR, elemental analysis, and energy-dispersive X-Ray spectroscopy (EDX)were applied to characterize these materials. The magnetic behavior of Fe(Ⅱ) and Nd(Ⅲ)complexes of poly(N-2-thiazolylacrylamide) was examined by a PPMS-9T magnetometer,exhibiting the characteristics of a soft ferromagnet. It is found that the Nd(Ⅲ) complex has an extremely high relative saturation magnetization of 35 emu/g.
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